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50 ml of 0.05 M HNO3 is added to 50 ml of 0.025 M KOH. Calculate the pH of the resultant solution. - Chemistry

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प्रश्न

50 ml of 0.05 M HNO3 is added to 50 ml of 0.025 M KOH. Calculate the pH of the resultant solution.

संख्यात्मक

उत्तर

Number of moles of HNO3 = 0.05 × 50 × 10−3

= 2.5 × 10−3

Number of moles of KOH = 0.025 × 50 × 10−3

= 1.25 × 10−3

Number of moles of HNO3 after mixing

= 2.5 × 10−3 – 1.25 × 10−3

= 1.25 × 10−3

∴ Concentration of HNO3 = `("Number of moles of HNO"_3)/("Volume is litre")`

After mixing, total volume = 100 ml = 100 × 10−3 L

∴ [H+] = `(1.25 xx 10^-3  "moles")/(100 xx 10^-3  "L")`

= 1.25 × 10−2 moles L−1

pH = –log [H+]

pH = –log (1.25 × 10−2)

= 2 – 0.0969

= 1.9031

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अध्याय 8: Ionic Equilibrium - Evaluation [पृष्ठ ३१]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
अध्याय 8 Ionic Equilibrium
Evaluation | Q 15. | पृष्ठ ३१
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