Advertisements
Advertisements
प्रश्न
Calculate the number of atoms present in 2 gram of crystal which has face-centred cubic
(FCC) crystal lattice having edge length of 100 pm and density 10 gcm−3
उत्तर
Given: Density (d) = 10 g cm−3
Edge length (a) = 100 pm = 100 × 10−10 cm.
Mass of crystal = 2 g
To find: Number of atoms
Formula: Density = Mass/Volume
Calculation: Density = Mass/Volume
∴ Volume = Mass/Density
∴ Volume = `"2g"/(10gcm^(−3))` = 0.2 cm3
Volume of unti cell = a3 = (100 × 10–10 cm)3 = 1 × 10−24 cm3
Number of unit cells in 2 g of crystal = total volume/volume of unit cell
`(0.2cm)^3/(1×10^(−24) cm^4)`
The given unit cell is of fcc type, therefore, it contains 4 atoms.
0.2 × 1024 unit cells will contain 4 × 0.2 × 1024 = 0.8 × 1024 atoms
= 8 × 1023 atoms
Number of atoms present in 2g of crystal is 8 × 1023 atoms
APPEARS IN
संबंधित प्रश्न
What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?
Define the following term: Primitive unit cells
How will you distinguish between the following pairs of terms : Crystal lattice and unit cell
Give the significance of a ‘lattice point’.
Which of the following lattices has the highest packing efficiency (i) simple cubic (ii) body-centred cubic and (iii) hexagonal close-packed lattice?
An ionic crystal lattice has limiting value of radius ratio as 0.414 to 0.732; the co-ordination number of its cation is _______.
(A) 6
(B) 4
(C) 3
(D) 12
Which of the following parameters are correct for triclinic lattice?
(A) α = β = γ = 90° and a = b = c
(B) α ≠ β ≠ γ = 90° and a ≠ b ≠ c
(C) α = γ = 90°, β ≠ 90° and a ≠ b ≠ c
(D) α ≠ β ≠ γ ≠ 90° and a ≠ b ≠ c
An ionic crystal lattice has `r^+/r` radius ratio of 0.320, its coordination number is __
(a) 3
(b) 4
(c) 6
(d) 8
In the complexes `[Fe(CN)_6]^(3-)` and `[pt(en) (H_2O)_2(NO_2 (Cl)^(2+)]``the respective oxidation numbers of central metal atoms are
1) +3 and +4
2) +6 and + 4
3) +6 and +3
4) +3 and + 3
For a crystal of sodium chloride, state:
1) The type of lattice in which it crystallises
2) The coordina~ion number of each sodium ion and chloride ion in the crystal lattice.
3) The number of sodium ions and chloride ions present in a unit cell of sodium chloride.
4) The structural arrangement of the sodium chloride crystaL
How will you obtain pure potassium permanganate (KMnO4) crystals from its ore, pyrolusite? Give the steps involved and the reactions.
Complete the following statement by selecting the correct alternative from the choices given:
In a face-centered cubic lattice, atom (A) occupies the comer positions and atom (B) occupies the face centre positions. If one atom of (B) is missing from one of the face-centered points, the formula of the compound is:
In a solid atom M occupies ccp lattice and `(1/3)` of tetrahedral voids are occupied by atom N. find the formula of solid formed by M and N.
A solid compound XY has NaCl structure. if the radius of the cation is 100 pm, the radius of the anion will be
The yellow colour in NaCl crystal is due to ____________.
Why ionic crystals are hard and brittle?
Crystals can be classified into basic crystal units, equal to ____________.
How many three-dimensional crystal lattices are possible?
The lattice site in a pure crystal cannot be occupied by ______.
AB crystallises in a body centred cubic lattice with edge length' a' equal to 387 pm The distance between two oppositely charged ions in the lattice is:
A particular solid is very hard and has a high melting point. In solid state, it is a non-conductor and in molten state, it is a conductor of electricity. Classify the solid ______.
How many unit cells are present in a cube-shaped ideal crystal of NaCI of mass 1.00 g? [Atomic masses : Na = 23, Cl = 35.5)