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Can we construct an electrochemical cell with two half-cells composed of ZnSO4 solution and zinc electrodes? Explain your answer. - Chemistry

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प्रश्न

Can we construct an electrochemical cell with two half-cells composed of ZnSO4 solution and zinc electrodes? Explain your answer.

संक्षेप में उत्तर

उत्तर

Yes, if the concentration of ZnSO4 in the two half cell is different, the electrode potential will be different making the cell possible.

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2023-2024 (March) Board Sample Paper

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संबंधित प्रश्न

Reduction potential of two metals M1 and M2 are \[\ce{E^0_{{M_1^{2+}|M_1}}}\] = −2.3 V and \[\ce{E^0_{{M_2^{2+}|M_2}}}\] = 0.2 V. Predict which one is better for coating the surface of iron.
Given: \[\ce{E^0_{{Fe^{2+}|Fe}}}\] = −0.44 V


Which of the following statement is not correct about an inert electrode in a cell?


Use the data given in below find out the most stable ion in its reduced form.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V


`E_(cell)^Θ` for some half cell reactions are given below. On the basis of these mark the correct answer.

(a) \[\ce{H^{+} (aq) + e^{-} -> 1/2 H_2 (g); E^Θ_{cell} = 0.00V}\]

(b) \[\ce{2H2O (1) -> O2 (g) + 4H^{+} (aq) + 4e^{-}; E^Θ_{cell} = 1.23V}\]

(c) \[\ce{2SO^{2-}_{4} (aq) -> S2O^{2-}_{8} (aq) + 2e^{-}; E^Θ_{cell} = 1.96V}\]

(i) In dilute sulphuric acid solution, hydrogen will be reduced at cathode.

(ii) In concentrated sulphuric acid solution, water will be oxidised at anode.

(iii) In dilute sulphuric acid solution, water will be oxidised at anode.

(iv) In dilute sulphuric acid solution, \[\ce{SO4^{2-}}\] ion will be oxidised to tetrathionate ion at anode.


Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode


Match the terms given in Column I with the units given in Column II.

Column I Column II
(i) Λm (a) S cm-¹
(ii) ECell (b) m-¹
(iii) K (c) S cm2 mol-¹
(iv) G* (d) V

Assertion: ECell should have a positive value for the cell to function.

Reason: `"E"_("cathode") < "E"_("anode")`


Cell reaction is spontaneous when


What should be the signs (positive/negative) for \[\ce{E^0_{cell}}\] and ΔG0 for a spontaneous redox reaction occurring under standard conditions?


What is an electrochemical cell? What does it consist of?


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