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प्रश्न
Define molecularity.
उत्तर
The molecularity of an elementary reaction refers to how many reactant molecules are involved in reactions.
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संबंधित प्रश्न
Answer the following in one or two sentences.
What is the relationship between coefficients of reactants in a balanced equation for an overall reaction and exponents in the rate law? In what case the coefficients are the exponents?
Answer the following in one or two sentences.
What is the rate-determining step?
A reaction takes place in two steps:
- \[\ce{NO_{(g)} + Cl2_{(g)} -> NOCl2_{(g)}}\]
- \[\ce{NOCl2_{(g)} + NO_{(g)} -> 2NOCl_{(g)}}\]
- Write the overall reaction.
- Identify the reaction intermediate.
- What is the molecularity of each step?
Which of the following is a unimolecular reaction?
Identify molecularity of following reaction:
\[\ce{C2H5I_{(g)} -> C2H_{4(g)} + HI_{(g)}}\]
Name the slowest step that determines the rate in a complex reaction.
Write an expression for instantaneous rate of reaction:
2N2O(g) → 4NO2(g) + O2(g).
What is the order of reaction?
Why is molecularity applicable for only elementary reactions whereas order of a reaction is applicable for elementary and complex reactions? Explain with suitable examples.
For a zero-order reaction, molecularity can never be equal to zero. Explain.
The rate determining step of a reaction is the step ____________.
For the elementary reaction, \[\ce{3H2_{(g)} + N2_{(g)} -> 2NH3_{(g)}}\] identify the correct relation among the following relations.
For the reaction \[\ce{2NO2 + F2 -> 2NO2F}\], following mechanism has been provided:
\[\ce{NO2 + F2 ->[slow] NO2F + F}\]
\[\ce{NO2 + F ->[fast] NO2F}\]
The rate expression of the above reaction can be written as:
The reaction \[\ce{2NO2Cl_{(g)} -> 2NO2_{(g)} + Cl2_{(g)}}\] takes place in two steps as
(i) \[\ce{NO2Cl_{(g)} -> NO2_{(g)} + Cl_{(g)}}\]
(ii) \[\ce{NO2Cl_{(g)} + Cl_{(g)} -> NO2_{(g)} + Cl2_{(g)}}\]
Identify the reaction intermediate.
A chemical species that is formed in one elementary step in the mechanism of complex reaction and consumed in the subsequent step is called ____________.
Consider the following elementary reaction;
\[\ce{2AB_{(g)} -> A2_{(g)} + B2_{(g)}}\]
The molecularity of the reaction is ____________.
A reaction involving two different reactants can never be a ______
Identify the molecularity of following elementary reaction:
NO(g) + O3(g) → NO3(g) + O(g)
The reaction takes place in two steps as
(i) \[\ce{NO2Cl(g) ->[k1] NO2(g) + Cl(g)}\]
(ii) \[\ce{NO2Cl(g) + Cl(g) ->[k2] NO2(g) + Cl2(g)}\]
Identify the reaction intermediate.
A certain reaction occurs in two steps as
(i) \[\ce{2SO2(g) + 2NO2(g) -> 2SO3(g) + 2NO(g)}\]
(ii) \[\ce{2NO(g) + O2(g) -> 2NO2(g)}\]
In the reaction:
How does a catalyst differ from reaction intermediate?
Define molecularity of reaction.