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Distinguish between the following pair of compounds using the test given within bracket. A lead salt and a zinc salt (using excess ammonium hydroxide) - Chemistry

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प्रश्न

Distinguish between the following pair of compounds using the test given within bracket.

A lead salt and a zinc salt (using excess ammonium hydroxide)

अंतर स्पष्ट करें

उत्तर

A lead salt and a zinc salt (using excess \[\ce{NH4OH}\])

\[\ce{pb(NO3)2 + 2NH4OH -> \underset{Chalky white ppt}{pb(OH)2↓} + 3(NH4)2SO4}\]

Insoluble in excess of \[\ce{NH4OH}\]

\[\ce{ZnSO4 + 2NH4OH -> \underset{White gelatinous ppt}{Zn(OH)2↓} + (NH4)2SO4}\]

With the excess of \[\ce{NH4OH}\] ppt. dissolves

\[\ce{Zn(OH)2 + (NH4)2SO4 + 2NH4OH -> \underset{Tetra amine zinc sulphate}{[Zn(NH3)4]SO4} + 4H2O}\]

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Action of Ammonium Hydroxide on Certain Salt Solutions
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 4: Analytical Chemistry - Exercise 7 [पृष्ठ ९१]

APPEARS IN

फ्रैंक Chemistry - Part 2 [English] Class 10 ICSE
अध्याय 4 Analytical Chemistry
Exercise 7 | Q 2.2 | पृष्ठ ९१

संबंधित प्रश्न

How will you distinguish between Ammonium hydroxide and Sodium hydroxide using copper sulphate solution?


Name the method used for preparation of the following salt from the list given below:
Zinc ion and Lead ion.


Choose the correct answer from the options given below :
Which salt solution is soluble in excess of NH4OH


Write the observation, and balanced equation for the following reaction:
Excess of ammonium hydroxide is added to a substance, obtained by adding hydrochloric acid to silver nitrate solution.


The following table shows the tests a student performed on four different aqueous solutions which are X,Y,Z and W. Based on the observations provided, Identify the cation present

Chemical Test

Observation Conclusion
To Solution X, ammonium hydroxide is added in minium quantity first and then in excess A dirty white precipitate is formed which dissolves in excess to form a clear solution (i)
To Solution Y, ammonium hydroxide is added in minimum quantity first and then in excess A pale blue precipitate is formed which dissolves in excess to form a clear inky blue solution (ii)
To solution W, A small quantity of sodium hydroxide solution is added and then in excess A white precipitate is formed which remains insoluble (iii)
To a salt Z, calcium hydroxide solution is added and then heated A pungent smelling gas turning moist red litmus paper blue is obtained (iv)

Identify the cation of the following case:
NaOH solution when added to solution (A) gives a reddish brown precipitate


What do you observe when caustic soda solution is added to the following solution: first a little and then in excess:

CuSO4

Write a balanced equation for this reaction.


Write balanced equation:

Copper sulphate solution with ammonium hydroxide solution.


Write balanced equation :

Copper sulphate solution with ammonium hydroxide solution.


Write balanced equation:

Copper sulphate solution with ammonium hydroxide solution. 


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