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प्रश्न
Finkelstein reaction is ______.
विकल्प
CH3CH2CH2Cl + Nal → CH3CH2CH2I + NaCl
CH3CH2CH2I + NaCl → CH3CH2CH2 − Cl + Nal
CH3 = CH2 + H − I → CH3CH2CH2I + CH3CHICH3
CH3CH2CH2Cl + NaBr → CH3CH2CH2Br + NaCl
उत्तर
Finkelstein reaction is CH3CH2CH2Cl + Nal → CH3CH2CH2I + NaCl.
Explanation:
Halide exchange reaction is the Finkelstein reaction in which alkyl chloride is converted to alkyl iodide.
The classic Finkelstein reaction entails the conversion of an alkyl chloride or an alkyl bromide to an alkyl iodide by treatment with a solution of sodium iodide in dry acetone. Sodium iodide is soluble in acetone, and sodium chloride and sodium bromide are not.
The reaction is driven toward products according to Le Chatelier's principle due to the precipitation of the salt insoluble in acetone. For example, in this case, chloropropane can be converted to iodopropane:
CH3CH2CH2Cl + Nal → CH3CH2CH2I + NaCl.