Advertisements
Advertisements
प्रश्न
Out of Mn3+ and Cr3+, which is more paramagnetic and why ?
(Atomic nos. : Mn = 25, Cr = 24)
उत्तर १
Mn3+ has four unpaired electrons (d4) in its valence shell whereas Cr3+ (d3) has three unpaired electrons. Thus, Mn3+ is more paramagnetic than Cr3+.
उत्तर २
Mn+3 = [Ar] 4s0 3d4 (4 unpaired e-)
Cr+3 = [Ar] 4s0 3d3 (3 unpaired e-)
Mn+3 has more no. of unpaired e- than Cr+3
APPEARS IN
संबंधित प्रश्न
The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Which element shows only +3 oxidation state?
How would you account for the following: Transition metals form complex compounds.
Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?
Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:
Electronic configurations
Give reasons: E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.
Two metallic elements A and B have the following standard oxidation potentials: A = 0·40v B = - 0·80v. What would you expect if element A was added to an aqueous salt solution of element B? Give a reason for your answer.
Match the properties given in Column I with the metals given in Column II.
Column I (Property) | Column II (Metal) | |
(i) | An element which can show +8 oxidation state | (a) \[\ce{Mn}\] |
(ii) | 3d block element that can show | (b) \[\ce{Cr}\] |
upto +7 oxidation state | (c) \[\ce{Os}\] | |
(iii) | 3d block element with highest melting point | (d) \[\ce{Fe}\] |
Give reasons for the following statement:
Transition metals and most of their compounds show paramagnetic behaviour.
The compounds of \[\ce{Ti^4+}\] ions are colourless due to ______.
Account for the following:
Zirconium (Zr) and Hafnium (Hf) are difficult to separate.