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प्रश्न
The volumes of gases A, B, C and D are in the ratio, 1 : 2 : 2 : 4 under the same conditions of temperature and pressure.
- Which sample of gas contains the maximum number of molecules?
- If the temperature and pressure of gas A are kept constant, then what will happen to the volume of A when the number of molecules is doubled?
- If this ratio of gas volume refers to the reactants and products of a reaction, which gas law is being observed?
- If the volume of A is actually 5.6 dm3 at STP, calculate the number of molecules in the actual Volume of D at STP (Avogadro's number is 6 × 1023).
- Using your answer from (iv), state the mass of D if the gas is dinitrogen oxide (N2O).
उत्तर
(i) D contains the maximum number of molecules because the volume is directly proportional to the number of molecules.
(ii) The volume will double because it is directly proportional to the number of molecules at constant temperature and pressure.
`("V"_1)/("V"_2)` = `("n"_1)/("n"_2)`
`("V"_1)/("V"_2)` = `("n"_1)/(2"n"_1)`
So, V2 = 2V1
(iii) Gay Lussac's law of combining volume is being observed.
(iv) The volume of D = 5.6 × 4 = 22.4 dm3, so the number of molecules = 6 x 1023 because according to mole concept 22.4 litre volume at STP has 6 x 1023 molecules.
(v) No. of moles of D = 1 because volume is 22.4 litre.
∴ Mass of N2O = (14 × 2 + 16 × 1) = 44 g
संबंधित प्रश्न
Water can split into hydrogen and oxygen under suitable conditions. The equations representing the change is: 2H2O(I) → 2H2 (g) + O2(g)
If a given experiment results in 2500cm3 of hydrogen being produced, what volume of oxygen is liberated at the same time under the same conditions of temperature and pressure?
When gases react their volumes bear a simple ratio to each other, under the same conditions of temperature and pressure. Who proposed this gas law?
What volume of oxygen would be required for complete combustion of 100L of ethane according to the following equation?
2C2H6 + 7O2 → 4CO2 + 6H2O
Propane burns in air according to the following equation:
\[\ce{C3H8 + 5O2 -> 3CO2 + 4H2O}\]
What volume of propane is consumed on using 1000 cm3 of air, considering only 20% of air contains oxygen?
1250 cc of oxygen was burnt with 300cc of ethane [C2H6]. Calculate the volume of carbon dioxide formed:
\[\ce{2C2H6 + 7O2 -> 4CO2 + 6H2O}\]
What volume of propane is burnt for every 500 cm3 of air used in the reaction under the same conditions? (assuming oxygen is `1/5`th of air)
\[\ce{C3H8 + 5O2 → 3CO2 + 4H2O}\]
450 cm3 of nitrogen monoxide and 200 cm3 of oxygen are mixed together and ignited. Caclulate the composition of resulting mixture.
\[\ce{2NO + O2 → 2NO2}\]
Ammonia may be oxidised to nitrogen monoxide in the presence of a catalyst according to the following equation.
\[\ce{4NH3 + 5O2 → 4NO + 6H2O}\]
If 27 litres of reactants are consumed, what volume of nitrogen monoxide is produced at the same temperature and pressure?
112 cm3 of H2S(g) is mixed with 120 cm3 of Cl2(g) at STP to produce HCl(g) and sulphur(s). Write a balanced equation for this reaction.
The reaction: \[\ce{4N2O + CH4 -> CO2 + 2H2O + 4N2}\] takes place in the gaseous state. If all volumes are measured at the same temperature and pressure, calculate the volume of dinitrogen oxide (N2O) required to give 150 cm3 of steam.
