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What is the Role of T-butyl Peroxide in the Polymerization of Ethene? - Chemistry

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प्रश्न

What is the role of t-butyl peroxide in the polymerization of ethene?

उत्तर

In polymerisation of ethene, source of free radical is needed to initiate the chain reaction. Such free radicals are usually produced by decomposition of peroxides like t-butyl peroxide or benzoyl peroxide.

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2015-2016 (March) Delhi Set 1

वीडियो ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्न

Which of the following is a natural polymer ? Buna-S, Proteins, PVC


What is the role of benzoyl peroxide in addition polymerisation of alkenes? Explain its mode of action with the help of an example.


Why should the monomers used in addition polymerisation through free radical pathway be very pure?


Match the polymers given in Column I with their chemical names given in Column II.

Column I Column II
(i) Nylon 6 (a) Polyvinyl chloride
(ii) PVC (b) Polyacrylonitrile
(iii) Acrilan (c) Polycaprolactum
(iv) Natural rubber (d) Low-density polythene
(v) LDP (e) cis-polyisoprene

Match the polymers given in Column I with the preferred mode of polymerisation followed by their monomers.

Column I Column II
(i) Nylon-6,6 (a) Free radical polymerisation
(ii) PVC (b) Ziegler-Natta polymerisation or coordination polymerisation
(iii) HDP (c) Anionic polymerisation
  (d) Condensation polymerisation

Assertion: Olefinic monomers undergo addition polymerisation.

Reason: Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.


Low density polythene and high density polythene, both are polymers of ethene but there is marked difference in their properties. Explain.


Which one of the following polymers are prepared by addition polymerisation?


Which one of the following polymers is prepared by addition polymerisation? 


\[\ce{X + C + Cl2 ->[High temperature][of about 1000 K] Y + CO}\];

\[\ce{Y + 2H2O -> Z + 2HCl}\]

Compound Y is found in polymeric chain structure and is an electron-deficient Molecule. Y must be:


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