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प्रश्न
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
उत्तर
(i) Isobutyl amine
(ii) 2-Phenylethylamine
Explanation:
Gabriel synthesis is a method for producing primary amines. When phthalimide is treated with ethanolic potassium hydroxide, it forms a potassium salt of phthalimide, which when heated with an alkyl halide and then alkaline hydrolyzed yields the corresponding primary amine.
APPEARS IN
संबंधित प्रश्न
Write a short note on Hoffmann bromamide degradation.
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Write the reactions of aliphatic primary amines with nitrous acid.
Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Which of the following compound is expected to be most basic?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Identify the product ‘C’ in the following reaction.
\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
