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प्रश्न
Why dissociation of HCN is suppressed by the addition of HCL?
उत्तर
HCN and HCL both dissociate to produce H+ ions which are common to both.
HCN is a weak electrolyte. It dissociates to a little extent.
HCN(aq) ⇌ H+(aq) + CN-
HCL is a strong ·electrolyte. It undergoes complete dissociation.
HCl(aq) → H+(aq) + Cl-(aq)
both HCN and HCL provide H+ ions.
The concentration of H+ ions in the solution increases due to the complete dissociation of HCL
According to Le-Chatelier's principle, the effect of the stress (the addition of H+ ions from HCL) applied to the ionisation equilibrium of HCN is reduced by shifting the equilibrium in the backward direction.
H+ ions combine with CN- ions to produce unionised HCN. Thus. the dissociation of HCN is suppressed by the addition of HCL.