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Why dissociation of HCN is suppressed by the addition of HCL? -

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प्रश्न

Why dissociation of HCN is suppressed by the addition of HCL?

संक्षेप में उत्तर

उत्तर

HCN and HCL both dissociate to produce H+ ions which are common to both.

HCN is a weak electrolyte. It dissociates to a little extent.
HCN(aq) ⇌ H+(aq) + CN

HCL is a strong ·electrolyte. It undergoes complete dissociation.
HCl(aq) → H+(aq) + Cl-(aq) 
both HCN and HCL provide H+ ions.

The concentration of H+ ions in the solution increases due to the complete dissociation of HCL

According to Le-Chatelier's principle, the effect of the stress (the addition of H+ ions from HCL) applied to the ionisation equilibrium of HCN is reduced by shifting the equilibrium in the backward direction.

H+ ions combine with CN- ions to produce unionised HCN. Thus. the dissociation of HCN is suppressed by the addition of HCL.

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