Advertisements
Advertisements
प्रश्न
18.0 g of water completely vapourises at 100°C and 1 bar pressure and the enthalpy change in the process is 40.79 kJ mol–1. What will be the enthalpy change for vapourising two moles of water under the same conditions? What is the standard enthalphy of vapourisation for water?
उत्तर
Enthalpy of a reaction is defined as the energy change per mole for the process. Therefore,
18 g of \[\ce{H2O}\] = 1 mole (ΔHVap = 40.79 kJ Mol–1)
Enthalpy change for vaporising 2 moles of \[\ce{H2O}\] = 2 × 40.79 = 81.58 kJ
ΔHVap = 40.79 kJ Mol–1.
APPEARS IN
संबंधित प्रश्न
The enthalpies of all elements in their standard states are ______.
The reaction of cyanamide, NH2CN(s), with dioxygen was carried out in a bomb calorimeter, and ΔU was found to be −742.7 kJ mol−1 at 298 K. Calculate enthalpy change for the reaction at 298 K.
\[\ce{NH_2 CN(g) + 3/2 O_2(g) -> N_2(g) + CO_2(g) + H_2O(l)}\]
Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at - 10.0°C. ΔfusH = 6.03 kJ mol-1 at 0°C.
Cp[H2O(l)] = 75.3 J mol-1 K-1
Cp[H2O(s)] = 36.8 J mol-1 K-1
Enthalpy of combustion of carbon to CO2 is –393.5 kJ mol–1. Calculate the heat released upon formation of 35.2 g of CO2 from carbon and dioxygen gas.
Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are -110 kJ mol-1, - 393 kJ mol-1, 81 kJ mol-1 and 9.7 kJ mol-1 respectively. Find the value of ΔrH for the reaction:
\[\ce{N2O_{4(g)} + 3CO_{(g)} → N2O_{(g)} + 3CO_{2(g)}}\]
Given
\[\ce{N_{2(g)} + 3H_{2(g)} -> 2NH_{3(g)}}\]; ΔrHθ = –92.4 kJ mol–1
What is the standard enthalpy of formation of NH3 gas?
Calculate the standard enthalpy of formation of CH3OH(l) from the following data:
\[\ce{CH3OH_{(l)} + 3/2 O2_{(g)} →CO_{2(g)} + 2H2O_{(l)}}\] ; ΔrHθ = –726 kJ mol–1
\[\ce{C_{(g)} + O_{2(g)} →CO_{2(g)}}\] ; ΔcHθ = –393 kJ mol–1
\[\ce{H_{2(g)} +1/2 O_{2(g)} → H2O_{(l)}}\] ; ΔfHθ = –286 kJ mol–1.
The value of ∆fHΘ for \[\ce{NH3}\] is – 91.8 kJ mol–1. Calculate enthalpy change for the following reaction:
\[\ce{2NH3(g) -> N2(g) + 3H2(g)}\]
For a reaction, A `→` B, enthalpy of reaction is −4.2 kJ mol−1 and enthalpy of activation is 9.6 kJ mol−1. The correct potential energy profile for the reaction is shown in option.
For a reaction, A `→` B, the enthalpy of reaction is −4.2 kJ mol−1 and the enthalpy of activation is 9.6 kJ mol−1. The correct potential energy profile for the reaction is shown in the option.