Advertisements
Advertisements
प्रश्न
If it were possible for a gas in a container to reach the temperature 0 K, its pressure would be zero. Would the molecules not collide with the walls? Would they not transfer momentum to the walls?
उत्तर
Since the pressure would be zero, the molecules would not collide with the walls and would not transfer momentum to the walls. This is because pressure of a gas is formed due to the molecule's collision with the walls of the container.
APPEARS IN
संबंधित प्रश्न
From a certain apparatus, the diffusion rate of hydrogen has an average value of 28.7 cm3 s–1. The diffusion of another gas under the same conditions is measured to have an average rate of 7.2 cm3 s–1. Identify the gas
[Hint: Use Graham’s law of diffusion: R1/R2 = (M2/M1)1/2, where R1, R2 are diffusion rates of gases 1 and 2, and M1 and M2 their respective molecular masses. The law is a simple consequence of kinetic theory.]
While gas from a cooking gas cylinder is used, the pressure does not fall appreciably till the last few minutes. Why?
Explain why cooking is faster in a pressure cooker.
A gas behaves more closely as an ideal gas at
A container of volume 50 cc contains air (mean molecular weight = 28.8 g) and is open to atmosphere where the pressure is 100 kPa. The container is kept in a bath containing melting ice (0°C). (a) Find the mass of the air in the container when thermal equilibrium is reached. (b) The container is now placed in another bath containing boiling water (100°C). Find the mass of air in the container. (c) The container is now closed and placed in the melting-ice bath. Find the pressure of the air when thermal equilibrium is reached.
Use R = 8.3 J K-1 mol-1
Is a slow process always isothermal? Is a quick process always adiabatic?
A gas is enclosed in a cylindrical can fitted with a piston. The walls of the can and the piston are adiabatic. The initial pressure, volume and temperature of the gas are 100 kPa, 400 cm3 and 300 K, respectively. The ratio of the specific heat capacities of the gas, Cp / Cv = 1.5. Find the pressure and the temperature of the gas if it is (a) suddenly compressed (b) slowly compressed to 100 cm3.
The initial pressure and volume of a given mass of a gas (Cp/Cv = γ) are p0 and V0. The gas can exchange heat with the surrounding. (a) It is slowly compressed to a volume V0/2 and then suddenly compressed to V0/4. Find the final pressure. (b) If the gas is suddenly compressed from the volume V0 to V0/2 and then slowly compressed to V0/4, what will be the final pressure?
Two glass bulbs of equal volume are connected by a narrow tube and are filled with a gas at 0°C at a pressure of 76 cm of mercury. One of the bulbs is then placed in melting ice and the other is placed in a water bath maintained at 62°C. What is the new value of the pressure inside the bulbs? The volume of the connecting tube is negligible.
The human body has an average temperature of 98°F. Assume that the vapour pressure of the blood in the veins behaves like that of pure water. Find the minimum atmospheric pressure which is necessary to prevent the blood from boiling. Use figure for the vapour pressures.
A barometer correctly reads the atmospheric pressure as 76 cm of mercury. Water droplets are slowly introduced into the barometer tube by a dropper. The height of the mercury column first decreases and then becomes constant. If the saturation vapour pressure at the atmospheric temperature is 0.80 cm of mercury, find the height of the mercury column when it reaches its minimum value.
On a winter day, the outside temperature is 0°C and relative humidity 40%. The air from outside comes into a room and is heated to 20°C. What is the relative humidity in the room? The saturation vapour pressure at 0°C is 4.6 mm of mercury and at 20°C it is 18 mm of mercury.
The temperature and humidity of air are 27°C and 50% on a particular day. Calculate the amount of vapour that should be added to 1 cubic metre of air to saturate it. The saturation vapour pressure at 27°C = 3600 Pa.
Use R = 8.3 J K-1 mol-1
The temperature and relative humidity in a room are 300 K and 20% respectively. The volume of the room is 50 m3. The saturation vapour pressure at 300 K 3.3 kPa. Calculate the mass of the water vapour present in the room.
Use R = 8.3 J K-1 mol-1
A bucket full of water is placed in a room at 15°C with initial relative humidity 40%. The volume of the room is 50 m3. (a) How much water will evaporate? (b) If the room temperature is increased by 5°C, how much more water will evaporate? The saturation vapour pressure of water at 15°C and 20°C are 1.6 kPa and 2.4 kPa respectively.
Use R = 8.3 J K-1 mol-1
A cuboidal container having dimensions 2 m × 1.5 m × 0.5 m holds a mixture of 12 g of He, 36 g of Ar, and 20 g of Ne, If the container is maintained at 300 K, Find the pressure exerted by the mixture (given MHe = 4, MAr = 40, MNe = 20).
If 1022 gas molecules each of mass 10-26 kg collide with a surface (perpendicular to it) elastically per second over an area of 1 m2 with a speed of 104 m/s, the pressure exerted by the gas molecules will be of the order of ______.
Air separated from the atmosphere by a column of mercury of length h = 15 cm is present in a narrow cylindrical two-soldered at one end. When the tube is placed horizontally the air occupies a volume V1 = 240 mm3. When it is set vertically with its open end upwards the volume of the air is V2 = 200 mm3. The atmospheric pressure during the experiment is 7n cm of Hg where n is a single digit number. n will be ______.