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प्रश्न
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
उत्तर
Ce(Z = 58)
Ce = 4f15d16s2
It is a strong oxidising agent.
⇒ Formationof Ce4+ is favoured because its noble gas configuration, but it is a strong oxidant due to the common +3 state. E° value Ce4+/ Ce3+ =+1.74 V
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संबंधित प्रश्न
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?
Match the statements given in Column I with the oxidation states given in Column II.
| Column I | Column II | |
| (i) | Oxidation state of Mn in MnO2 is | (a) + 2 |
| (ii) | Most stable oxidation state of Mn is | (b) + 3 |
| (iii) | Most stable oxidation state of | (c) + 4 |
| Mn in oxides is | (d) + 5 | |
| (iv) | Characteristic oxidation state of lanthanoids is | (e) + 7 |
Match the property given in Column I with the element given in Column II.
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
| (ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
| (iii) | Radioactive lanthanoid | (c) Lu |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
| (f) Dy |
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.
Zr(Z = 40) and Hf(Z = 72) have similar atomic and ionic radii because of ______
Mischmetal is an alloy consisting mainly of ______.
Write a note on lanthanoids.
State a reason for the following:
La(OH)3 is more basic than Lu(OH)3.
