Advertisements
Advertisements
प्रश्न
The equivalent conductance of `"M"/36` solution of a weak monobasic acid is 6 mho cm2 equivalent−1 and at infinite dilution is 400 mho cm2 equivalent−1. The dissociation constant of this acid is ____________.
पर्याय
1.25 × 10−6
6.25 × 10−6
1.25 × 10−4
6.25 × 10−5
उत्तर
The equivalent conductance of `"M"/36` solution of a weak monobasic acid is 6 mho cm2 equivalent−1 and at infinite dilution is 400 mho cm2 equivalent−1. The dissociation constant of this acid is 6.25 × 10−6.
Explanation:
α = `Λ/(Λ_∘) = 6/400`
Ka = α2C
= `6/400 xx 6/400 xx 1/36`
= 6.25 × 10−6
APPEARS IN
संबंधित प्रश्न
| Electrolyte | KCl | KNO3 | HCl | NaOAC | NaCl |
| Λ_ (S cm mol−1) |
149.9 | 145.0 | 426.2 | 91.0 | 126.5 |
Calculate \[\ce{Λ^∘_{HOAC}}\] using appropriate molar conductances of the electrolytes listed above at infinite dilution in water at 25°C.
Faradays constant is defined as ____________.
Which of the following electrolytic solution has the least specific conductance?
A conductivity cell has been calibrated with a 0.01 M, 1 : 1 electrolytic solution (specific conductance (κ = 1.25 × 10−3 S cm−1) in the cell and the measured resistance was 800 Ω at 25°C. The cell constant is, ____________.
Conductivity of a saturated solution of a sparingly soluble salt AB (1 : 1 electrolyte) at 298 K is 1.85 × 10−5 S m−1. Solubility product of the salt AB at 298 K `(Λ_"m"^∘)_"AB"` = 14 × 10−3 S m2 mol−1.
Why does the conductivity of a solution decrease on dilution of the solution?
Arrange the following solutions in the decreasing order of specific conductance.
i) 0.01 M KCl
ii) 0.005 M KCl
iii) 0.1 M KCl
iv) 0.25 M KCl
v) 0.5 M KCl
Why is AC current used instead of DC in measuring the electrolytic conductance?
0.1 M NaCl solution is placed in two different cells having cell constant 0.5 and 0.25 cm−1 respectively. Which of the two will have a greater value of specific conductance.
Ionic conductance at infinite dilution of Al3+ and \[\ce{SO^{2-}_4}\] are 189 and 160 mho cm2 equiv−1. Calculate the equivalent and molar conductance of the electrolyte Al2(SO4)3 at infinite dilution.
