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What Are Lanthanoids? - Chemistry

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प्रश्न

What are lanthanoids?

उत्तर

The series involving the filling of 4f-orbitals following lanthanum La (Z = 57) is called lanthanoid series. The elements present in this series are called lanthanoids.

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2013-2014 (March)

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संबंधित प्रश्‍न

Define lanthanoid contraction.


Account for the following :

Zr and Hf have almost similar atomic radii.


What are the different oxidation states exhibited by the lanthanoids?


Write the electronic configurations of the elements with the atomic numbers 61, 91, 101 and 109.


Write the different oxidation states of iron


Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?


Account for the following: 

Zn, Cd and Hg are soft metals.


What is Lanthanoid contraction?


What is lanthanoid contraction? Write the.............


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?


Match the compounds/elements given in Column I with uses given in Column II.

  Column I (Compound/element) Column II (Use)
(i)  Lanthanoid oxide (a) Production of iron alloy
(ii)  Lanthanoid (b) Television screen
(iii)  Misch metal (c) Petroleum cracking
(iv)  Magnesium based alloy is constituent of (d) Lanthanoid metal + iron
(v)  Mixed oxides of lanthanoids are employed (e) Bullets
    (f) In X-ray screen

Match the statements given in Column I with the oxidation states given in Column II.

  Column I Column II
(i) Oxidation state of Mn in MnO2 is (a) + 2
(ii) Most stable oxidation state of Mn is (b) + 3
(iii) Most stable oxidation state of  (c) + 4
  Mn in oxides is (d) + 5
(iv) Characteristic oxidation state of lanthanoids is (e) + 7

Match the property given in Column I with the element given in Column II.

  Column I (Property) Column II (Element)
(i) Lanthanoid which shows
+4 oxidation state
(a) Pm
(ii) Lanthanoid which can show +2
oxidation state
(b) Ce
(iii) Radioactive lanthanoid (c) Lu
(iv) Lanthanoid which has 4f7
electronic configuration in +3
oxidation state
(d) Eu
(v) Lanthanoid which has 4f14
electronic configuration in
+3 oxidation state
(e) Gd
    (f) Dy

On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].


On the basis of Lanthanoid contraction, explain the following:

Stability of the complexes of lanthanoids.


On the basis of Lanthanoid contraction, explain the following:

Radii of 4d and 5d block elements.


Which of the following pairs has the same ionic size?


The titanium (Z = 22) compound that does not exist is:-


Zr(Z = 40) and Hf(Z = 72) have similar atomic and ionic radii because of ______ 


Write any two consequences of Lanthanoid Contraction.


State a reason for the following:

La(OH)3 is more basic than Lu(OH)3.


Why is Mn2+ ion more stable than Fe2+ ion?

(Atomic numbers of Mn = 25 and Fe = 26)


Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.

Reason: Lanthanoids do not show Lanthanoid contraction.


Name an important alloy which contains some of the lanthanoid metals.


Mention alloy uses.


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