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Why work done in vacuum is zero? - Chemistry

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प्रश्न

Why work done in vacuum is zero?

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उत्तर

A free expansion means expansion against zero opposing force. Such expansion occurs in a vacuum. When the gas expands in a vacuum, there is no opposing force, that is, Pext = 0. The work done by a system during such expansion is W = – Pext ∆V = 0.
Thus, work done in a vacuum is zero.

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