मराठी

Write Chemical Equation in Support of Your Answer. Out of Cl and Ch2- Cl, Which One is More Reactive Towards Nucleophilic Substitution Reaction and Why? - Chemistry

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प्रश्न

Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 

टीपा लिहा

उत्तर

  CH2 - Cl , will be more reactive towards  SN2  reaction as in case of  reaction as in case of Cl the back side attack will be very difficult.

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2018-2019 (March) 56/3/2

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संबंधित प्रश्‍न

Chlorobenzene is extremely less reactive towards a nucleophilic substitution reaction. Give two reasons for the same.


The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.


Write the product formed on reaction of D-glucose with Br2 water.


Out of (CH3)3 C-Br and (CH3)3 C-I, which one is more reactive towards SN1 and why? 


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Arrange the following compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a)
(b)
(c)

Haloarenes are less reactive than haloalkanes and haloalkenes. Explain.


Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.


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