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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write electrode reactions and overall cell reaction when Leclanche's dry cell generates electricity. - Chemistry

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प्रश्न

Write electrode reactions and overall cell reaction when Leclanche's dry cell generates electricity.

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उत्तर

Electrode reactions are as follows:

  1. Oxidation at anode:
    \[\ce{Zn_{(s)} -> Zn^{2+}_{ (aq)} + 2e^{-}}\]
  2. Reduction at cathode:
    \[\ce{2NH^{+}_{4(aq)} + 2MnO_{2(s)} + 2e^{-} -> Mn_2O_{3(s)} + 2NH_{3(aq)} + H_2O_{(l)}}\]
  3. Overall cell reaction:
    \[\ce{Zn_{(s)} + 2NH^+_{4(aq)} + 2MnO2 -> Zn^{2+}_{ (aq)} + Mn2O_{3(s)} + 2NH_{3(aq)} + H2O_{(l)}}\]
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