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A weak monobasic acid of 0.04% dissociated in 0.025 M solution. Calculate the pH of the solution. -

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Question

A weak monobasic acid of 0.04% dissociated in 0.025 M solution. Calculate the pH of the solution.

Numerical

Solution

Given: % α of monobasic acid = 0.04, c = 0.025

Now, \[\ce{HA + H2O <=> H3O+ + A-}\]

% α = α × 100

∴ α = `(% α)/100`

= `0.04/100`

= 4 × 10−4

Now, [H+] or [H3O+] = α.C

= 4 × 10−4 × 0.025 M

= 4 × 10−5 M

Now, pH = − log10 [H+]

∴ pH = − log10 [1 × 10−5]

pH = 5

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Ionisation of Acids and Bases
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