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Question
An engine takes in 5 moles of air at 20°C and 1 atm, and compresses it adiabatically to `1/10^"th"` of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is ______.
Options
42
46
45
41
Solution
An engine takes in 5 moles of air at 20°C and 1 atm, and compresses it adiabatically to `1/10^"th"` of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is 46.
Explanation:
Given: Number of moles in a sample of diatomic ideal gas made up of rigid molecules is n = 5, temperature of gas is Ti = 20°C pressure of gas is P = 1 atm, the gas goes through an adiabatic compression, Vf = `"V"_"i"/10` the change in internal energy of the gas during the adiabatic process is ΔU = X kJ.
To find: The value of X.
For an adiabatic process:
`"T"_"i""V"_"i"^(gamma-1) = "T"_"f""V"_"f"^(gamma-1)`
`"T"_"f" = "T"_"i" ("V"_"i"/"V"_"f")^(gamma-1)`
γ = `7/5` for diatomic gas with rigid molecules.
Tf = (20 + 273) ×(10)7/5-1
= 736 K
ΔU = `1/2"fnR"("T"_"f"-"T"_"i") = 1/2xx5xx5xx8.31xx443`
ΔU = 46016 J
ΔU = 46 KJ
But ΔU = X KJ
So, X = 46