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Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids. Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do - Chemistry

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Question

Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.

Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not use their 4f orbital for bonding.

Options

  • Both assertion and reason are true, and reason is the correct explanation of the assertion.

  • Both assertion and reason are true but reason is not the correct explanation of assertion.

  • Assertion is not true but reason is true.

  • Both assertion and reason are false.

MCQ

Solution

Assertion is not true but reason is true.

Explanation:

Actinoids are more reactive than lanthanoids as they involve their 5d-orbital in the bond formation process while due to effectively shielded and greater nuclear charge 4f-orbitals are not available for bonding. Thus, lanthanoids comparatively form less complexes than actinoids. 

Assertion is not true but reason is true.

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Chapter 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [Page 114]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 61 | Page 114

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