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Question
Calcium carbide is used for the artificial ripening of fruits. Actually the fruit ripens because of the heat evolved while calcium carbide reacts with the moisture. During this reaction calcium hydroxide and acetylene gas are formed. If 200 cm3 of acetylene is formed from a certain mass of calcium carbide, find the volume of oxygen required and carbon dioxide formed during the complete combustion. The combustion reaction can be represented as below.
\[\ce{2C2H2_{(g)} + 5O2_{(g)}-> 4CO2_{(g)} + 2H2O_{(g)}}\]
Solution
Applying Gay-Lussac's law on the equation,
\[\ce{\underset{2 Vol.}{2C2H2_{(g)}} + \underset{5 Vol.}{5O2_{(g)}}-> \underset{4 Vol.}{4CO2_{(g)}} + 2H2O_{(g)}}\]
As 2 volumes of acetylene require = 5 volumes of oxygen
1 volume of acetylene require = `5/2` volumes of oxygen
∴ 200 cm3 of acetylene will require = `5/2 xx 200`
= 500 cm3 of oxygen
Further, 2 volumes of acetylene produce = 4 volumes of CO2
1 volume of acetylene produce = `4/2` volumes of CO2
∴ 200 cm3 of acetylene will produce = `4/2 xx 200`
= 400 cm3 of CO2
Hence, 500 cm3 of oxygen and 400 cm3 of carbon dioxide is formed.
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