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CO is isoelectronic with (i) NOX+ (ii) NX2 (iii) SnclX2 (iv) NOX2− - Chemistry

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Question

\[\ce{CO}\] is isoelectronic with

(i) \[\ce{NO+}\]

(ii) \[\ce{N2}\]

(iii) \[\ce{Sncl2}\]

(iv) \[\ce{NO^{-}2}\]

Short Note

Solution

(i) \[\ce{NO+}\]

(ii) \[\ce{N2}\]

Explanation:

The species having the same number of electrons are known as isoelectronic species. 

The number of electrons in \[\ce{CO}\] species is 14;8 electrons from oxygen atom and 6 electrons from carbon atom.

The number of electrons in \[\ce{NO+}\] is 14;8 electrons from oxygen atom, 7 electrons from nitrogen atom and 1 electron will be subtracted due to the positive charge on the species.

The number of electrons in \[\ce{N2}\] is 14;7 from each nitrogen atom.

The number of electrons in \[\ce{SnCl2}\] is 84;50 from the tin atom and 17 from each chlorine atom.

The number of electrons in \[\ce{NO^{-}2}\] is 24;7 from nitrogen atom, 8 from each oxygen atom and 1 from the negative charge on the species.

Hence \[\ce{NO+}\] and \[\ce{N2}\] are the isoelectronic species of \[\ce{CO}\].

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Bonding in Some Homonuclear Diatomic Molecules
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Chapter 4: Chemical Bonding and Molecular Structure - Multiple Choice Questions (Type - I) [Page 43]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 4 Chemical Bonding and Molecular Structure
Multiple Choice Questions (Type - I) | Q 25 | Page 43
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