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Question
\[\ce{CO}\] is isoelectronic with
(i) \[\ce{NO+}\]
(ii) \[\ce{N2}\]
(iii) \[\ce{Sncl2}\]
(iv) \[\ce{NO^{-}2}\]
Solution
(i) \[\ce{NO+}\]
(ii) \[\ce{N2}\]
Explanation:
The species having the same number of electrons are known as isoelectronic species.
The number of electrons in \[\ce{CO}\] species is 14;8 electrons from oxygen atom and 6 electrons from carbon atom.
The number of electrons in \[\ce{NO+}\] is 14;8 electrons from oxygen atom, 7 electrons from nitrogen atom and 1 electron will be subtracted due to the positive charge on the species.
The number of electrons in \[\ce{N2}\] is 14;7 from each nitrogen atom.
The number of electrons in \[\ce{SnCl2}\] is 84;50 from the tin atom and 17 from each chlorine atom.
The number of electrons in \[\ce{NO^{-}2}\] is 24;7 from nitrogen atom, 8 from each oxygen atom and 1 from the negative charge on the species.
Hence \[\ce{NO+}\] and \[\ce{N2}\] are the isoelectronic species of \[\ce{CO}\].
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RELATED QUESTIONS
Give reasons for the following:
Ethyne molecule is linear.
Assertion (A): Among the two \[\ce{O - H}\] bonds in \[\ce{H2O}\] molecule, the energy required to break the first \[\ce{O - H}\] bond and the other \[\ce{O - H}\] bond is the same.
Reason (R): This is because the electronic environment around oxygen is the same even after breakage of one \[\ce{O - H}\] bond.