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Question
Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place, further show:
- which of the electrode is negatively charged,
- the carriers of the current in the cell, and
- individual reaction at each electrode.
Solution
The galvanic cell corresponding to the given redox reaction can be represented as:
\[\ce{Zn | Zn^{2+}_{(aq)} || Ag+_{(aq)} | Ag}\]
- Zn electrode is negatively charged because at this electrode, Zn oxidizes to Zn2+and the leaving electrons accumulate on this electrode.
- Ions are the carriers of current in the cell.
- The reaction taking place at Zn electrode can be represented as:
\[\ce{Zn_{(s)} -> Zn^{2+}_{(aq)} + 2e-}\]
And the reaction taking place at Ag electrode can be represented as:
\[\ce{Ag+_{ (aq)} + e- -> Ag_{(s)}}\]
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