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Karnataka Board PUCPUC Science Class 11

Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place, further show: (i) which of the electrode is negatively charged, - Chemistry

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Question

Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place, further show:

  1. which of the electrode is negatively charged,
  2. the carriers of the current in the cell, and
  3. individual reaction at each electrode.
Answer in Brief

Solution

The galvanic cell corresponding to the given redox reaction can be represented as:

\[\ce{Zn | Zn^{2+}_{(aq)} || Ag+_{(aq)} | Ag}\]

  1. Zn electrode is negatively charged because at this electrode, Zn oxidizes to Zn2+and the leaving electrons accumulate on this electrode.
  2. Ions are the carriers of current in the cell.
  3. The reaction taking place at Zn electrode can be represented as:

\[\ce{Zn_{(s)} -> Zn^{2+}_{(aq)} + 2e-}\]

And the reaction taking place at Ag electrode can be represented as:

\[\ce{Ag+_{ (aq)} + e- -> Ag_{(s)}}\]

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Redox Reactions in Terms of Electron Transfer Reactions - Competitive Electron Transfer Reactions
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Chapter 8: Redox Reactions - EXERCISES [Page 283]

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NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 8 Redox Reactions
EXERCISES | Q 8.30 | Page 283
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