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Question
Devise a scheme for the synthesis of n-butane using CH3I as the only source of carbon. Is it possible to obtain propane in pure state by applying this scheme? Give a reason for your answer.
Short Note
Solution
Carry out Wurtz reaction twice.
No, propane cannot be prepared in fairly pure state.
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Chlorobenzene - Wurtz-fittig Reaction
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Assertion: Tertiary butyl bromide undergoes Wurtz reaction to give 2,2,3,3 tetramethyl butane.
Reason: In Wurtz reaction, when same alkyl halides react with sodium in dry ether to give hydrocarbon; the hydrocarbon formed contains double the number of carbon atoms present in the alkyl halide.
