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Give two reactions in which acidified K2Cr2O7 is used as an oxidizing agent. -

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Question

Give two reactions in which acidified K2Cr2O7 is used as an oxidizing agent.

Answer in Brief

Solution

Oxidation of I of Kl to I2:

K2Cr2O7 + 6KI + 7H2SO4 → 4K2SO4 + Cr2(SO4)3 + 7H2O + 3I2

Oxidation of H2S to S:

K2Cr2O7 + 4H2SO4 + 3H2S → K2SO4 + Cr2(SO4)3 + 7H2O + 3S

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Chemical Properties of Elements of Groups 16, 17 and 18
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