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Haloarenes are less reactive than alkyl halides towards nucleophilic substitution because ____________ in aryl halide. -

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Question

Haloarenes are less reactive than alkyl halides towards nucleophilic substitution because ____________ in aryl halide.

Options

  • of less stable carbonium ion

  • of large C-X bond energy

  • of negative inductive effect

  • of more polar C-X bond

MCQ
Fill in the Blanks

Solution

Haloarenes are less reactive than alkyl halides towards nucleophilic substitution because of large C-X bond energy in aryl halide.

Explanation:

The C-X bond takes on a partial double bond nature due to resonance. Haloarenes have a stronger and shorter C-X bond than haloalkanes. As a result, breaking the C-X bond in haloarenes is challenging.

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