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Identify the group that exerts electron withdrawing resonance effect. -

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Question

Identify the group that exerts electron withdrawing resonance effect.

Options

  • \[\ce{- NHR}\]

  • \[\ce{- COOH}\]

  • \[\ce{- OR}\]

  • \[\ce{- OH}\]

MCQ

Solution

\[\ce{- COOH}\]

Explanation:

The \[\ce{- COOH}\]  group has an electron withdrawing resonance effect when compared to the other options. It has an adjacent π-system that has π-bond to an electronegative atom (i.e. - C = 0), which deactivates the aromatic ring by reducing the electron density on the ring due to a resonance withdrawing action.

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Theoretical Basis of Organic Reactions
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