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If [A] is the concentration of A at any time t and [A]0 is the concentration at t = 0, then for the 1st order reaction, the rate equation can be written as ____________. -

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Question

If [A] is the concentration of A at any time t and [A]0 is the concentration at t = 0, then for the 1st order reaction, the rate equation can be written as ____________.

Options

  • k = `2.303/"t" log_10  (["A"])/(["A"]_0)`

  • [A] = [A]0 e−kt

  • k = `2.303/"t" log_10  (["A"]_0)/(["A"]_0 - ["A"])`

  • k = `2.303/"t" log_10  (["A"]_0 - ["A"])/(["A"]_0)`

MCQ
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Solution

If [A] is the concentration of A at any time t and [A]0 is the concentration at t = 0, then for the 1st order reaction, the rate equation can be written as [A] = [A]0 e−kt.

Explanation:

For the first order reaction, the rate equation can be written as,

k = `2.303/"t" log_10  (["A"]_0)/(["A"]_"t")`

∴ kt = `ln  (["A"]_0)/(["A"]_"t")`

Taking antilog on both sides,

[A] = [A]0 e−kt

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