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Question
In an ionic solid r(+) = 1.6 Å and r(−) = 1.864 Å. Use the radius ratio rule to the edge length of the cubic unit cell is ______ Å.
Options
2
4
6
8
MCQ
Fill in the Blanks
Solution
In an ionic solid r(+) = 1.6 Å and r(−) = 1.864 Å. Use the radius ratio rule to the edge length of the cubic unit cell is 4 Å.
Explanation:
`"r"_((+))/"r"_((-)) = 1.6/1.864` = 0.858 ....[Body-Centred Cubic (BCC)]
∴ a = `(2(1.6 + 1.864))/sqrt3` = 4 Å
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