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Question
ln which of the following reactions, both oxidised and reduced forms of the same compound are obtained?
Options
Aldol condensation
Cannizzaro's reaction
Riemer-Tiemann reaction
Kolbe's synthesis
MCQ
Solution
Cannizzaro's reaction
Explanation:
The oxidised and reduced versions of the same aldehyde are generated in Cannizzaro's reaction. It's a reaction of disproportionation.
\[\begin{array}{cc}
\ce{O}\phantom{.................................................................}\\
||\phantom{.................................................................}\\
\ce{\underset{Formaldehyde (No α-H atom)}{2H - C - H} + \underset{{(50%)}}{NaOH} -> \underset{Methyl alcohol (reduced product)}{CH3 - OH} + \underset{Sodium formate (oxidised product)}{HCOONa}}
\end{array}\]
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Chemical Properties of Aldehydes and Ketones
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