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Match the ions given in Column I with their nature given in Column II. Column I Column II (i) CHX3−O∙∙∙∙−C⊕H−CHX3 (a) Stable due to resonance (ii) FX3−C⊕ (b) Destabilised due to inductive effect - Chemistry

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Question

Match the ions given in Column I with their nature given in Column II.

Column I Column II
(i) \[\ce{CH3 - \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - \overset{⊕}{C}H - CH3}\] (a) Stable due to resonance
(ii) \[\ce{F3 - \overset{⊕}{C}}\]  (b) Destabilised due to inductive effect

(iii) \[\begin{array}{cc}
\phantom{........}\ce{CH3}\\
\phantom{......}|\\
\ce{CH3 - C^Θ}\\
\phantom{......}|\\
\phantom{........}\ce{CH3}
\end{array}\]

(c) Stabilised by hyperconjugation
(iv) \[\ce{CH3 - \overset{⊕}{C}H - CH3}\] (d) A secondary carbocation
Match the Columns

Solution

Column I Column II
(i) \[\ce{CH3 - \overset{\bullet\bullet}{\underset{\bullet\bullet}{O}} - \overset{⊕}{C}H - CH3}\] (a) Stable due to resonance
(ii) \[\ce{F3 - \overset{⊕}{C}}\]  (b) Destabilised due to inductive effect

(iii) \[\begin{array}{cc}
\phantom{........}\ce{CH3}\\
\phantom{......}|\\
\ce{CH3 - C^Θ}\\
\phantom{......}|\\
\phantom{........}\ce{CH3}
\end{array}\]

(b) Destabilised due to inductive effect
(iv) \[\ce{CH3 - \overset{⊕}{C}H - CH3}\] (c) Stabilised by hyperconjugation
(d) A secondary carbocation
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Fundamental Concepts in Organic Reaction Mechanism - Inductive Effect
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Chapter 12: Organic Chemistry Some Basic Principles and Techniques - Multiple Choice Questions (Type - I) [Page 154]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 12 Organic Chemistry Some Basic Principles and Techniques
Multiple Choice Questions (Type - I) | Q 54 | Page 154
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