Advertisements
Advertisements
Question
On the basis of thermochemical equations (a), (b) and (c), find out which of the algebric relationships given in options (i) to (iv) is correct.
(a) \[\ce{C (graphite) + O2 (g) -> CO2 (g) ; ∆_rH = xkJ mol^{-1}}\]
(b) \[\ce{C (graphite) + 1/2 O2 (g) -> CO (g) ; ∆_rH = ykJ mol^{-1}}\]
(c) \[\ce{CO (g) + 1/2 O2 (g) -> CO2 (g) ; ∆_r H = zkJ mol^{-1}}\]
Options
z = x + y
x = y – z
x = y + z
y = 2z – x
Solution
x = y + z
Explanation:
When we add equations (b) and (c) we will get equation (a) hence, Algebraic sum of y and z will give x, x = y + z.
APPEARS IN
RELATED QUESTIONS
Heat of combustion is always ___________.
Molar heat of vapourisation of a liquid is 4.8 kJ mol–1. If the entropy change is 16 J mol–1 K–1, the boiling point of the liquid is
Write the unit of molar heat capacity.
What are state and path functions? Give two examples.
\[\ce{∆_f U^Θ}\] of formation of \[\ce{CH4 (g)}\] at certain temperature is – 393 kJ mol–1. The value of \[\ce{∆_f H^Θ}\] is ______.
The standard molar entropy of \[\ce{H2O (l)}\] is 70 JK–1 mol–1. Will the standard molar entropy of \[\ce{H2O (s)}\] be more, or less than 70 JK–1 mol–1?
The molar enthalpy of vapourisation of acetone is less than that of water. Why?
Derive the relationship between ∆H and ∆U for an ideal gas. Explain each term involved in the equation.
The molar heat of formation of NH4NO3 (s) is −367.54 kJ and those of N2O (g), H2O (l) are 81.46 and −285.8 kJ respectively at 25°C and atmosphere pressure. The difference of ΔH and ΔE of the reaction \[\ce{NH4NO3(s) -> N2O (g) + 2H2O (l)}\] is ______ kJ.
A cylinder of gas supplied by Bharat Petroleum is assumed to contain 14 kg of butane. If a normal family requires 20,000 kJ of energy per day for cooking, butane gas in the cylinder last for ______ Days. (Δ Hc of C4 H10 = - 2658 JK per mole)
