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Question
State Dobereiner’s Law of Triads with suitable examples.
Solution
Dobereiner’s Law of Triads: “When elements are arranged in order of increasing atomic masses, groups of three elements (known as triads), having similar chemical properties are obtained. The atomic mass of the middle element of the triad being equal to the arithmetic mean of the atomic masses of the other two elements.”
Examples:
Similarity in properties
Element | Lithium | Sodium | Potassium |
At. weight | 7.0 | 23.0 | 39.0 |
- All of them are metals. Average wt. of sodium 7 + 39/2 = 46/2 = 23
- All have valency 1.
- They react with water form alkalis and hydrogen gas.
Halogen Group:
\[\ce{Cl}\] | \[\ce{Br}\] | \[\ce{I}\] |
35.5 | 80 | 127 |
- All of them are non-metals
- All have valency one (1).
- Each reacts with water to form acid.
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Did Dobereiner’s triads also exist in the columns of Newlands’ Octaves? Compare and find out.
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In Dobereiner’s triads Li, Na, K, the atomic masses of Lithium and Potassium are 6.9 and 39.1 respectively, then what will be the atomic mass of sodium?
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