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State the Trends in Physical Properties on Moving Down the Group. Give an Example to Illustrate. -

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Question

State the trends in physical properties on moving down the group. Give an example to illustrate.

Solution

The melting and boiling points of metals decrease on going down the group. Example: Observe the trend in group 1 elements given in the following table:

Metals m.p b.p
Li 180.5°C 1347°C
Na 94.5°C 883°C
K 63.5°C 774°C

From the above table, it is clear that m.p. and b.p. decrease from Li to K.
The melting and boiling points of non-metals increase on going down the group.
Example: Observe the trend in Group 17 elements given in the following table:

Non-metals m.p. b.p. Physical state
Fluorine -219.6°C -187°C Gas
Chlorine -101°C -34.6°C Gas
Bromine -7.2°C +58.8°C Liquid
Iodine +113.6°C +183°C Solid

From the above table, it is clear that m.p. and b.p. increase from F to I.

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