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The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be ____________. -

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Question

The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be ____________.

Options

  • +26.4 kcal

  • −67.6 kcal

  • −120.6 kcal

  • +52.8 kcal

MCQ
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Solution

The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be −67.6 kcal.

Explanation:

\[\ce{CO + 1/2O2 -> CO2}\]

∆H = `∆_"f""H"^0 ("CO"_2) - [∆_"f""H"^0 ("CO") + 1/2∆_"f""H"^0 ("O"_2)]`

∴ = −94.0 kcal − (−26.4 kcal) ........[∵ ∆fH0(O2) = 0]

= −67.6 kcal

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Thermochemistry
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