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Question
The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be ____________.
Options
+26.4 kcal
−67.6 kcal
−120.6 kcal
+52.8 kcal
MCQ
Fill in the Blanks
Solution
The heat of formations of CO(g) and CO2(g) are −26.4 kcal and −94.0 kcal respectively. The heat of combustion of carbon monoxide will be −67.6 kcal.
Explanation:
\[\ce{CO + 1/2O2 -> CO2}\]
∆H = `∆_"f""H"^0 ("CO"_2) - [∆_"f""H"^0 ("CO") + 1/2∆_"f""H"^0 ("O"_2)]`
∴ = −94.0 kcal − (−26.4 kcal) ........[∵ ∆fH0(O2) = 0]
= −67.6 kcal
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Thermochemistry
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