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Question
The number of optical isomers possible for 3, 4-dichloropentan-2-ol is ______.
Options
Eight
Four
Sixteen
Two
MCQ
Fill in the Blanks
Solution
The number of optical isomers possible for 3, 4-dichloropentan-2-ol is eight.
Explanation:
\[\begin{array}{cc}
\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{Cl}\phantom{...}\ce{Cl}\phantom{...}\ce{H}\\
|\phantom{.....}|\phantom{.....}|\phantom{.....}|\phantom{.....}|\\
\ce{H - C - C^* - C^* - C^* - C - H}\\
|\phantom{.....}|\phantom{.....}|\phantom{.....}|\phantom{.....}|\\
\phantom{.....}\underset{\text{3, 4 - dichloropentan - 2- ol}}{\ce{H}\phantom{....}\ce{H}\phantom{....}\ce{H}\phantom{....}\ce{H}\phantom{....}\ce{H}}
\end{array}\]
Number of chiral carbon atoms (n) = 3
∴ Optical isomers possible are 2n = 23 = 8
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Optical Isomerism in Halogen Derivatives
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