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The standard electrode potential of the two half cells are given below: NiX2++2eX−⟶Ni,EX0=−0.25Volt ZnX2++2eX−⟶Zn,EX0=−0.77Volt The voltage of cell formed by combining the two half cells would be? -

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Question

The standard electrode potential of the two half cells are given below:

\[\ce{Ni^{2+} + 2e^{-} -> Ni, E_0 = - 0.25 Volt}\]

\[\ce{Zn^{2+} + 2e^{-} -> Zn, E_0 = - 0.77 Volt}\]

The voltage of cell formed by combining the two half cells would be?

Options

  • –0.52 Volt

  • –1.02 Volt

  • +0.52 Volt

  • + 1.02 Volt

MCQ

Solution

+0.52 Volt

Explanation:

\[\ce{Ni^{2+} + 2e^{-} -> Ni, E^{o}_{red} = - 0.25 V cathode}\]

\[\ce{Zn^{2+} + 2e^{-} -> Zn, E^{o}_{red} = - 0.77 V anode}\]

\[\ce{E^{o}_{cell} = - 0.25 V - (- 0.77 V) = - 0.25 V + 0.77 V = 0.52 V}\]

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