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The structures of six organic compounds are shown: Identify two of the compounds that are members of the same homologous series but are not isomers. - Chemistry

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Question

The structures of six organic compounds are shown:

A

\[\begin{array}{cc}
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\\
|\phantom{....}|\phantom{....}|\phantom{....}|\\
\ce{H - C - C = C - C - H}\\
|\phantom{.............}|\\
\ce{H}\phantom{............}\ce{H}
\end{array}\]

B

\[\begin{array}{cc}
\phantom{.......}\ce{H}\phantom{.....}\ce{O}\\
\phantom{.......}|\phantom{.....}//\\
\ce{H - C - C}\\
\phantom{......}|\phantom{.....}\backslash\\
\phantom{...........}\ce{H}\phantom{.....}\ce{O - H}
\end{array}\]

C

\[\begin{array}{cc}
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\\
|\phantom{....}|\phantom{....}|\phantom{....}|\\
\ce{H - C - C - C - C - H}\\
|\phantom{....}|\phantom{....}|\phantom{....}|\\
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}
\end{array}\]

D

\[\begin{array}{cc}
\ce{H}\phantom{...}\ce{H}\\
|\phantom{....}|\\
\ce{H - C - C - H}\\
|\phantom{....}|\\
\ce{H}\phantom{...}\ce{O}\\
\phantom{.......}\backslash\\
\phantom{.........}\ce{H}
\end{array}\]

E

\[\begin{array}{cc}
\ce{H}\\
|\\
\ce{H - C - H}\\
\ce{H}\phantom{....}\phantom{....}\ce{H}\\
|\phantom{....}|\phantom{....}|\\
\ce{H - C - C - C - H}\\
|\phantom{....}|\phantom{....}|\\
\ce{H}\phantom{...}\ce{H}\phantom{...}\ce{H}
\end{array}\]

F

\[\begin{array}{cc}
\ce{H}\phantom{...}\ce{H}\\
|\phantom{....}|\\
\ce{C = C}\\
|\phantom{....}|\\
\ce{H}\phantom{...}\ce{H}
\end{array}\]

  1. Identify two of the compounds that are members of the same homologous series but are not isomers.
  2. Which two compounds are isomers of each other?
  3. F can be prepared from D. Give a chemical equation for the reaction.
Answer in Brief

Solution

  1. A and F are two of the compounds that are members of the same homologous series but are not isomers.
  2. C and E are two compounds that are isomers of each other.
  3. \[\ce{C2H5OH ->[170^\circ C][conc{.} H2SO4] C2H4 + H2O}\]
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Organic Compounds
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2024-2025 (April) Specimen Paper
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