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What happens when ammonia solution is added first dropwise and then in excess to the following solution: CuSO4 Write balanced equation for these reaction. - Chemistry

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Question

What happens when ammonia solution is added first dropwise and then in excess to the following solution:

CuSO4

Write a balanced equation for this reaction.

Short Note

Solution

\[\ce{\underset{\text{blue}}{CuSO4} + 2NH4OH -> \underset{\text{pale blue ppt.}}{Cu(OH)2\downarrow} + \underset{\text{colourless in solution}}{(NH4)2SO4}}\]

With excess of NH4OH , ppt. dissolves

\[\ce{Cu(OH)2 + 4NH4OH -> \underset{(Deep Blue Solution)}{\underset{Tetrammine copper (II) hydroxide}{[Cu(NH3)4](OH2)}} + 4H2O}\]

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Action of Ammonium Hydroxide on Certain Salt Solutions
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Chapter 4: Analytical Chemistry: Uses of Ammonium Hydroxide and Sodium Hydroxide - Exercise 4 [Page 68]

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Selina Concise Chemistry [English] Class 10 ICSE
Chapter 4 Analytical Chemistry: Uses of Ammonium Hydroxide and Sodium Hydroxide
Exercise 4 | Q 4. (i) | Page 68
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