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Question
What is the action of the following reagents on ethyl amine?
Nitrous acid
Solution
Ethyl amine on reaction with nitrous acid forms ethyl diazonium salts as very unstable intermediate which decomposes immediately by reaction with solvent water to give ethanol.
\[\ce{\underset{Ethyl amine}{C2H5 - NH2} + HNO2 ->[273-278 K][(NaNO2 + HCl)] \underset{Ethyl diazonium chloride}{[C2H5 - \overset{⊕}{N2}Cl^⊖]} ->[H2O] \underset{Ethanol}{C2H5 - OH} + N2 ↑ + HCl}\]
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