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When 0.5 gram of sulphur is burnt to form SO2, 4.6 kJ of heat liberated. Calculate enthalpy of formation of SO2(g). (Atomic mass : S = 32, O = 16) -

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Question

When 0.5 gram of sulphur is burnt to form SO2, 4.6 kJ of heat liberated. Calculate enthalpy of formation of SO2(g). (Atomic mass : S = 32, O = 16)

Options

  • - 294.4 kJ mol-1

  • - 172.4 kJ mol-1

  • - 81.2 kJ mol-1

  • - 258.6 kJ mol-1

MCQ

Solution

- 294.4 kJ mol-1 

Explanation:

\[\ce{S + O2 -> SO2; \Delta H_f = - 4.6 kJ}\]

0.5 g of sulphur on burning produce 1 g of SO2.

∴ 32 g of sulphur on burning will produce 64 g of SO2.

∴  `Delta "H"_"f" = (- 4.6 " kJ") xx 64 = - 294.4` kJ mol-1

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Thermochemistry
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