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Which of the following is Clemmensen reduction? -

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Question

Which of the following is Clemmensen reduction?

Options

  • \[\begin{array}{cc}
    \phantom{..................................}\ce{H}\\
    \phantom{..................................}|\\
    \ce{-C ≡ N + 2[H] ->[SnCl2][dil. HCl] CH = NH*HCl ->[H3O+] - C = O + NH4Cl}
    \end{array}\]

  • \[\ce{- CH = O ->[H2N - NH2][- H2O] R - CH = N - NH2 ->[KOH/ethyleneglycol][\Delta] - CH3 + N2}\]

  • \[\ce{- CO - + 4[H] ->[Zn-Hg/conc.HCl][\Delta] - CH2 - + H2O}\]

  • \[\ce{- CO - Cl ->[H2][Pd-BaSO4] - CHO + HCl}\]

MCQ

Solution

\[\ce{- CO - + 4[H] ->[Zn-Hg/conc.HCl][\Delta] - CH2 - + H2O}\]

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Chemical Properties of Aldehydes and Ketones
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