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Which one is most reactive towards nucleophilic addition reaction? -

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Question

Which one is most reactive towards nucleophilic addition reaction?

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MCQ

Solution

Explanation:

Aromatic aldehydes react to nucleophilic addition more readily than aromatic ketones. As a result, benzaldehyde (C6H5CHO) has a higher nucleophilic addition reactivity than acetophenone (C6H5COCH3). The presence of electron donating groups such as −CH3, −C2H5 in aromatic aldehydes discourages nucleophilic assault because the carbonyl carbon becomes less electrophilic.

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