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Why do the d-block elements form coloured compounds? -

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Question

Why do the d-block elements form coloured compounds?

Answer in Brief

Solution

  1. Compounds (or ions) of many d-block elements or transition metals are coloured. This is due to the presence of one or more unpaired electrons in (n - 1) d orbital. The transition metals have incompletely filled (n  - 1) d orbital.
  2. The energy required to promote one or more electrons within the d orbitals involving d-d transitions is very low
  3. Therefore transition metal ions absorb the radiation in the visible region and appear coloured.
  4. Colour of ions of d block elements depends on the number of unpaired electrons in (n  - 1) d orbital. The ions having equal number of unpaired electrons have similar colour.
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D-block Elements - Some Important Compounds of Transition Elements
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