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You have a mixture of three liquids A, B and C. There is a large difference in the boiling points of A and rest of the two liquids i.e., B and C. Boiling point of liquids B and C are quite close. - Chemistry

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Question

You have a mixture of three liquids A, B and C. There is a large difference in the boiling points of A and rest of the two liquids i.e., B and C. Boiling point of liquids B and C are quite close. Liquid A boils at a higher temperature than B and C and boiling point of B is lower than C. How will you separate the components of the mixture. Draw a diagram showing set up of the apparatus for the process.

Long Answer

Solution

Liquids which have different boiling points vaporize at different temperatures. The vapours are cooled and then liquids so formed are collected separately. Liquid A can be separated from B and C due to the large difference in boiling points. Liquid B and Liquid C have boiling points very close to each other and cannot be separated by simple distillation and are separated by fractional distillation. Liquid B distilled first since the order of boiling points of A, B and C is as follows: B < C < A.

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Introduction of Methods of Purification of Organic Compounds
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Chapter 12: Organic Chemistry Some Basic Principles and Techniques - Multiple Choice Questions (Type - I) [Page 156]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 12 Organic Chemistry Some Basic Principles and Techniques
Multiple Choice Questions (Type - I) | Q 64 | Page 156
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