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प्रश्न
Arrange the following in increasing order of their basic strength :
उत्तर
Reason:-
The -CH3 group will increase the electron density on the benzene ring because of its +I effect, while the NO2 group will decrease the electron density on the benzene ring because of its ‒I effect. Hence, the C6H5-NH2 molecule having -CH3 group will be more basic than C6H5-NH2. Also, it will be more basic than the C6H5-NH2 molecule with the NO2 group.
संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
Arrange the following: C2H5NH2, C2H5OH, (CH3)3N – in the increasing order of their boiling point
How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?
Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2
Complete the following acid-base reaction and name the product:
\[\ce{(C2H5)3N + HCl ->}\]
Account for the following:
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Give plausible explanation for each of the following:
Why are aliphatic amines stronger bases than aromatic amines?
Complete the following reaction:
\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Which one of the following compounds will liberate CO2, when treated with NaHCO3?
