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प्रश्न
How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?
उत्तर
\[\ce{Cl-(CH2)4-Cl ->[2 mol NaCN][EtOH] NC-(CH2)4-CN ->[H2/Ni][Reduction] \underset{Hexan-1, 6-diamine}{H2NH2C-(CH2)4-CH2NH2}}\]
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संबंधित प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
Arrange the following in increasing order of their basic strength :
- Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
- Write the IUPAC names of all the isomers.
- What type of isomerism is exhibited by different pairs of amines?
How will you convert Benzene into aniline?
How will you convert Benzene into N, N-dimethylaniline?
Complete the following acid-base reaction and name the product:
\[\ce{CH3CH2CH2NH2 + HCl ->}\]
Arrange the following:
In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Choose the most correct option.
Which one of the following compounds has the highest boiling point?
The CORRECT decreasing order of solubility in water will be ____________.
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.
Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
Which one of the following compounds will liberate CO2, when treated with NaHCO3?