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प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Account for the following :
(CH3)2NH is more basic than (CH3)3N in an aqueous solution
उत्तर
In (CH3)3N, there is maximum steric hindrance and least solvation, but in (CH3)2NH, the solvation is more and the steric hindrance is less than in (CH3)3N. Although the +I effect is less because there are two methyl groups, di-methyl amine is still a stronger base than tri-methyl amine.
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संबंधित प्रश्न
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2
Arrange the following:
In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Accomplish the following conversion:
Aniline to p-bromoaniline
Tertiary amines have lowest boiling points because ________________
Among the following isomeric amines, an amine having highest boiling point is:
Acetic acid exist as dimer in benzene due to
The hydrogen bond is shortest in
Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
